AP® Chemistry 2022 Scoring Guidelines (e) For the correct calculated value: Accept one of the following: • E °=0.80 V +1.66 V =2.46 V • = E −. cell red ox =0.80 V ( 1.66 V) 2.46 V . 1 point (f) For the correct answer and a valid justification: Negative. The reaction has a positive value of E °Prepare for the AP Chemistry exam with this official free-response questions document from the College Board. It contains seven questions that require you to apply your knowledge of chemical concepts and skills to various scenarios. You will have 105 minutes to complete all the questions.

Sign in to access your AP or Pre-AP resources and tools including AP Classroom.AP* Kinetics Free Response Questions page 2 Mechanism 3 is correct. The rate law shows that the slow reaction must involve one Y, consistent with mechanism 3. Mechanisms 1 and 2 would involve both [X] and [Y] in the rate law, not consistent with the rate law. 1987 a) three points; one each for form of rate law, HgCl2 exponent, C2O4 2¯ exponent

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